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Chapter 5 201

Copyright © 2017 Pearson Education, Inc.

52.

If the number of carbons is 30, C

n

H

2

n

+

2

=

C

30

H

62

. A compound with molecular formula C

30

H

50

is missing

12 hydrogens. Because it has no rings, squalene has 6

p

bonds

1

12

>

2

=

6

2

.

53.

a.

C C

C

H CH

3

C

H

C C

C

H

H H

C

CH

3

(

(

E

)-2-methyl-2,4-hexadiene

Z

)-2-methyl-2,4-hexadiene

H

CH

3

CH

3

CH

3

CH

3

b.

H

C

H

C

CH

2

CH

2

H

H

(

E

)-1

(

eneidatpeh-5,

Z

)-1,5-heptadiene

C

H CH

3

C

H

C

H

C

CH

2

CH

2

H

C

H H

C

CH

3

c.

1,4-pentadiene

H

C

H

C

CH

2

H

H

C

H H

C

d.

H

C C

C

H H

C

CH

3

CH

3

CH

3

H

C C

C

H

H

C

CH

3

CH

3

CH

3

(2

E,

4

Z

)-3-methyl-2,4-hexadiene

(2

E,

4

E

)-3-methyl-2,4-hexadiene

H

C C

C

H H

C

CH

3

CH

3

CH

3

H

C C

C

H

H

C

CH

3

CH

3

CH

3

(2

Z,

4

Z

)-3-methyl-2,4-hexadiene

(2

Z,

4

E

)-3-methyl-2,4-hexadiene

54.

a.

CH

3

CH

2

NH

3

+

+

Br

b.

CH

3

C CH

3

OH

O

c. 

CH

3

CH

CH

3

CCH

3

CH

3

+

+

Cl

55.

Only one name is correct.

a.

2-pentene

b.

correct

c.

3-methyl-1-hexene (the parent hydrocarbon is the longest chain that contains the functional group)