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Chapter 24 779

Copyright © 2017 Pearson Education, Inc.

7.

seven: one mole of NADH is obtained from each round of

b

-oxidation.

16

carbons

14

carbons

+

1 acetyl-CoA

2nd round

12

carbons

+

1 acetyl-CoA

3rd round

10

carbons

+

1 acetyl-CoA

8

carbons

+

1 acetyl-CoA

6

carbons

+

1 acetyl-CoA

4

carbons

+

1 acetyl-CoA

2 acetyl-CoA

4th round

5th round

6th round

7th round

1st round

of

-oxidation

8.

The OH group attacks the

g

-phosphorus of ATP.

O

2

O

3

POCH

2

HO

OH

CH

2

OH

HO

O

O

Ad

O

+

O

2

O

3

POCH

2

HO

OH

CH

2

OPO

3

HO

2

+

O

fructose-6-phosphate

ATP

fructose-1,6-bisphosphate

ADP

+

H

+

P

O

OO

P

O

OO

P

O

Ad

OO

P

O

OO

P

O

9.

The reaction that follows the oxidation of glyceraldehyde-3-phosphate to 1,3-bisphosphoglycerate (the

conversion of 1,3-bisphosphoglycerate to 3-phosphoglycerate) is highly exergonic. Therefore, as

1,3-bisphosphoglycerate is converted to 3-phosphoglycerate, glyceraldehyde-3-phosphate will be converted

to 1,3-bisphosphoglycerate to replenish it.

glyceraldehyde-3-phosphate

1,3-bisphosphoglycerate

3-phosphoglycerate

10.

two; each molecule of d-glucose is converted to two molecules of glyceraldehyde-3-phosphate, and each

molecule of glyceraldehyde-3-phosphate requires one molecule of

NAD

+

for it to be converted to one

molecule of pyruvate.

11.

acetaldehyde reductase

12.

a ketone

13.

thiamine pyrophosphate

14.

N

R

H H

H

H B

+

CH

2

NH

2

NH

2

OH

CH

3

N

R

+

B

CH

3

C

O

O

O