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Chapter 11 409
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6.
Indicate how each of the following compounds can be prepared using the given starting material:
a.
b.
7.
What alcohols are formed from the reaction of ethylene oxide with the following organocuprates?
a.
1
CH
3
CH
2
CH
2
2
2
CuLi
b.
CuLi
2
8.
Which of the following can be used as a reactant in a Heck or Suzuki reaction?
Br
Br
Br
Br
Br
Br
Br
9.
Show how the following compounds can be prepared by:
a.
a Heck reaction
b.
a Suzuki reaction
1.
NH
2
O
2.
10.
What are the products of the following reactions?
a.
O
O
B
CH
3
CH
2
+
PdL
2
HO
−
Br
b.
+
PdL
2
(CH
3
CH
2
CH
2
)
3
N
Br
11.
Using any needed reagents, show how the following synthesis can be carried out:
Br
H
?
O