408 Chapter 11
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Chapter 11 Practice Test
1.
Which is more reactive, an organocadmium compound (electronegativity of Cd
=
1.5) or an organolead
compound (electronegativity of lead
=
1.6)?
2.
Which of the following alkyl halides could be used to form a Grignard reagent?
Br
Br
OH
Br
Br
N
H
3.
What are the products of the following reactions?
a.
b.
c.
−
4.
What are the products of the following reactions?
a.
Br
+
PdL
2
(CH
3
CH
2
)
3
N
+ (CH
3
CH
2
CH
2
)
2
CuLi
Br
+
B(OR)
2
PdL
2
HO
−
Br
b.
Br
+
PdL
2
(CH
3
CH
2
)
3
N
+ (CH
3
CH
2
CH
2
)
2
CuLi
Br
+
B(OR)
2
PdL
2
HO
−
Br
c.
Br
+
PdL
2
(CH
3
CH
2
)
3
N
+ (CH
3
CH
2
CH
2
)
2
CuLi
Br
+
B(OR)
2
PdL
2
HO
−
Br
5.
What are the products of the following reactions?
a.
b.
c.
Grubbs
catalyst
Grubbs
catalyst
Grubbs
catalyst




