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408 Chapter 11

Copyright © 2017 Pearson Education, Inc.

Chapter 11 Practice Test

1.

Which is more reactive, an organocadmium compound (electronegativity of Cd

=

1.5) or an organolead

compound (electronegativity of lead

=

1.6)?

2.

Which of the following alkyl halides could be used to form a Grignard reagent?

Br

Br

OH

Br

Br

N

H

3.

What are the products of the following reactions?

a.

b.

c.

4.

What are the products of the following reactions?

a.

Br

+

PdL

2

(CH

3

CH

2

)

3

N

+ (CH

3

CH

2

CH

2

)

2

CuLi

Br

+

B(OR)

2

PdL

2

HO

Br

b.

Br

+

PdL

2

(CH

3

CH

2

)

3

N

+ (CH

3

CH

2

CH

2

)

2

CuLi

Br

+

B(OR)

2

PdL

2

HO

Br

c.

Br

+

PdL

2

(CH

3

CH

2

)

3

N

+ (CH

3

CH

2

CH

2

)

2

CuLi

Br

+

B(OR)

2

PdL

2

HO

Br

5.

What are the products of the following reactions?

a.

b.

c.

Grubbs

catalyst

Grubbs

catalyst

Grubbs

catalyst