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652 Chapter 18

Copyright © 2017 Pearson Education, Inc.

7.

Draw the major product(s) of the following reactions:

OCH

3

CH

2

CH

3

Cl

Cl

OCH

3

NO

2

+

+

+

+

CH

3

Cl

CH

3

O

HNO

3

Cl

2

H

2

SO

4

FeCl

3

AlCl

3

f.

b.

c.

d.

e.

CH

C

3

O

NO

2

+

H

2

SO

4

a.

H

2

CrO

4

8.

Indicate whether each of the following statements is true or false:

a.

Benzoic acid is more reactive than benzene toward electrophilic

aromatic substitution.

T F

b.

para

-Chlorobenzoic acid is more acidic than

para

-methoxybenzoic acid.

T F

c.

A CH

CH

2

group is a meta director.

T F

d.

para

-Nitroaniline is more basic than

para

-chloroaniline.

T F

9.

Draw the resonance contributors for the carbocation intermediate that is formed when benzene reacts with

an electrophile

1

Y

+

2

.