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Chapter 18 651

Copyright © 2017 Pearson Education, Inc.

Chapter 18 Practice Test

1.

Name the following:

CH

3

NO

2

Br

Br

Br

COOH

CH

2

CH

3

OH

Cl

a.

b.

c.

d.

2.

Rank the following compounds from most reactive to least reactive toward reaction with Br

2

>

FeBr

3

:

Br

CH

N

H

C

3

CH

2

CH

3

O

NHCH

C

3

O

3.

For each of the following pairs, circle the stronger acid:

COOH

Cl

COOH

CH

3

NH

3

+

+

CH

3

NH

3

OCH

3

or

or

a.

c.

OH

NO

2

OH

Br

COOH

CH

3

COOH

or

or

b.

d.

4.

a.

Which is more reactive in a nucleophilic substitution reaction,

para

-bromonitrobenzene or

para

-bromoethylbenzene?

b.

Which is more reactive in an electrophilic substitution reaction,

para

-bromonitrobenzene or

para

-bromoethylbenzene?

5.

What acid anhydride would you use in the synthesis of propylbenzene?

6.

Draw the mechanism for the formation of the nitronium ion from nitric acid and sulfuric acid.