Bruice - Chimica Organica

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Chapter 15 499
Copyright © 2017 Pearson Education, Inc.
57. a. SOCl2 CH3 CH2CH2OH
OCH 2CH 2CH 3
−
CH3CH2CH2 Br
OCH2CH 2CH3
OH CH3 3
CH 3 O CH
3
Cl CH CH3
C
O
C
O
C
O
C
O
C
O and
b. SOCl2 (CH3 )2 CH(CH 2)2OH
O(CH2)2CH(CH3)2
−
(CH3 ) CH(CH2 )2 2 Br
O(CH2)2CH(CH 3)2
OH CH 3 Cl CH 3
O CH
3 CH3
CH3
C
O
C
O
C
O
C
O
C
O and
c.
CH3CH2CH2
SOCl2
CH 3CH2CH2
CH3CH2 OH
CH3CH2CH2 OCH2CH3
CH 3CH2CH2 O−
CH3 CH2Br
CH3CH 2CH 2 OCH 2CH3
C
OH
O
C
Cl
O
C
O
C
O
C
O and
d. SOCl 2 CH3OH
3
CH 3Br
C
OH CH 2
O
C
Cl CH 2
O
C
OCH CH2
O
C
O CH
2
O
C
OCH CH2 3
O and
58. a. isopropyl alcohol and HCl
b. aqueous sodium hydroxide
c. ethylamine
d. water and HCl
59. a.
O
O O
O
O O
c. a.
O
O O
O
O O
c.
b.
H2N
C
NHCH3
O
d. CH3CH 2 O
O
O
b.
H 2N
C
NHCH3
O
d. CH3CH2 O
O
O