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838 Chapter 27

Copyright © 2017 Pearson Education, Inc.

30.

a.

Because it is a polyamide (and not a polyester), it is a nylon.

b.

H

2

N

CH

2

NH

2

and HOC(CH

2

)

6

COH

O O

31.

Each ester group in the compound reacts with HCl

>

CH

3

OH in the same way.

C

O OCH

2

CH

2

O

O

+

B

C

O

C

OH

+

+

+

OCH

3

CH

3

OH

C

H Cl

H B

O OCH

2

CH

2

O

C

O

C

OH

H

C

O OCH

2

CH

2

O

C

O

C

OCH

3

OH

C

O OCH

2

CH

2

O

C

O

C

H

OCH

3

OH

B

C

O OCH

2

CH

2

O

C

O

C

+

O

C OCH

3

+

HOCH

2

CH

2

O

C OCH

3

O

C

O

O

C

H

32.

A copolymer is composed of more than one kind of monomer. Because the initially formed carbocation

can rearrange, two different monomers (the unrearranged carbocation and the rearranged carbocation) are

involved in formation of the polymer.

CHCCH

3

CH

3

CH

3

+

CH

2

CHCCH

3

CH

3

CH

3

+

1,2-methyl shift

unrearranged monomer

rearranged monomer

CH

2