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156 Chapter 3

Copyright © 2017 Pearson Education, Inc.

Chapter 3 Practice Test

1.

Name the following compounds:

a.

b.

OH

c.

OH

2.

Using Newman projections, draw the following conformers of hexane considering rotation about the

C

3

¬

C

4

bond:

a.

the most stable of all the conformers

b.

the least stable of all the conformers

c.

a gauche conformer

3.

What are the common and systematic names of the following compounds?

a.

CH

3

CH

2

CHCH

3

Cl

b.

CH

3

CHCH

2

CH

2

CH

2

OH

CH

3

c.

Br

4.

Rank the three compounds in each set from highest boiling to lowest boiling.

a.

3 2 2 2 2

3 2 2

3 2 2 2

CH CH CH CH CH Br

CH CH CH Br

CH CH CH CH Br

b.

3 2 2 2 3

3 2 2 2

3 2 2 2

CH CH CH CH CH

CH CH CH CH OH CH CH CH CH Cl

c.

CH

3

CH

3

C CCH

3

CH

3

CH

3

CH

3

CH

3

CH

2

CH

2

CH

2

CH

2

CH

2

CH

2

CH

3

CH

3

CHCH

2

CH

2

CH

2

CH

2

CH

3

CH

3

5.

Name the following compounds:

a.

CH

3

CHCH

2

CH

2

CHCH

2

CH

3

CH

3

OH

c.

Br

CH

3

b.

CH

3

CH

2

CHOCH

2

CH

3

CH

2

CH

2

CH

2

CH

3

d.

CH

3

CHCHCH

2

CH

2

CH

2

Cl

CH

2

CH

3

Cl