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40

Spectroscopy Problems

Copyright © 2017 Pearson Education, Inc.

64.

A compound with molecular formula C

14

H

20

O

2

gives the

1

H NMR spectrum shown below. Identify the

compound. Important IR data are given below.

IR Data:

3030 cm

-

1

medium

1500

cm

-

1

sharp, medium

1690

cm

-

1

strong

1380

cm

-

1

medium

1600

cm

-

1

sharp, medium

0

1

2

3

4

5

6

7

8

9

1

1

2

2

6

6

2

65.

Compound A, with molecular formula C

10

H

12

O, gives the

1

H NMR spectrum shown below. Identify the

compound. Important IR data are given below.

IR Data:

1703 cm

-

1

(strong absorption)

2700–2800 cm

-

1

(two week absorptions)

1500

and 1600 cm

-

1

(two medium absorptions)

1

10

9

8

7

6

5

4

3

2

1