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140 Chapter 3

Copyright © 2017 Pearson Education, Inc.

24.

CH

3

OH

common

=

methyl alcohol

systematic

=

methanol

CH

3

CH

2

OH

common

=

ethyl alcohol

systematic

=

ethanol

CH

3

CH

2

CH

2

OH

common

=

propyl alcohol

or

n

-propyl alcohol

systematic

=

1

@

propanol

22.

a. 1.

methoxyethane

2.

ethoxyethane

3.

4-methoxyoctane

4.

1-isopropoxy-3-methylbutane

5.

1-propoxybutane

6.

2-isopropoxyhexane

b.

No.

c. 1.

ethyl methyl ether

2.

diethyl ether

3.

no common name

4.

isopentyl isopropyl ether

5.

butyl propyl ether

6.

no common name

23.

a.

1-pentanol

primary

b.

5-chloro-2-methyl-2-pentanol

tertiary

c.

5-methyl-3-hexanol

secondary

d.

7-methyl-3,5-octanediol (Notice that because there

are two OH groups, the suffix is “diol.”)

both alcohol groups are secondary

CH

3

CH

2

CH

2

CH

2

OH

common

=

butyl alcohol or

n

-butyl alcohol

systematic

=

1

@

butanol

CH

3

CH

2

CH

2

CH

2

CH

2

OH

common

=

pentyl alcohol or

n

-pentyl alcohol

systematic

=

1

@

pentanol

CH

3

CH

2

CH

2

CH

2

CH

2

CH

2

OH

common

=

hexyl alcohol

or

n

-hexyl alcohol

systematic

=

1

@

hexanol

25.

CH

3

CCH

2

CH

2

CH

3

OH

CH

3

OH

CH

3

CH

2

CCH

2

CH

3

OH

OH

CH

3

CH

3

C

OH

CHCH

3

CH

3

CH

3

OH

2-methyl-2-pentanol

3-methyl-3-pentanol

2,3-dimethyl-2-butanol

26.

a.

4-chloro-3-ethylcyclohexanol

secondary

b.

7,8-dimethyl-3-nonanol

secondary

c.

1-bromo-5,5-dimethyl-3-heptanol

secondary

d.

4-methylcyclohexanol

secondary