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Chapter 2 109

Copyright © 2017 Pearson Education, Inc.

Chapter 2 Practice Test

1.

Which compound is the stronger acid?

a.

CH

3

CHCH

2

OH or CH

3

CHCH

2

OH

Cl

F

b. 

HBr  or  HI

c. 

Cl

Cl

CH

3

CCH

2

OH or

Cl

Cl

CH

2

CHCH

2

OH

d. 

CH

4

or NH

3

2.

Which compound is the stronger base?

a. 

CH

3

CH

2

NH

2

or CH

3

CH

2

OH

b. 

F

-

or I

-

3.

Draw a circle around the strongest base and draw a square around the weakest base.

CH

3

CO

CH

3

O

CH

3

NH CH

3

NH

2

CH

3

OH

O

4.

The following compounds are drawn in their acidic forms, and their

p

K

a

values are given.

Draw the form in which each compound will predominantly exist at

pH

=

8.

+

3

3 2

3

3 2 3

+

a

a

a

a

H

CH COOH CH CH OH CH OH

CH CH NH

p 4.8

p 15.9

p

2.5

p 11.2

K

K

K

K

=

=

= −

=

5.

a.

Write the acid–base reaction that occurs when methylamine is added to water.

b.

Does the above reaction favor reactants or products?

6.

a.

What is the conjugate base of

NH

3

?

b.

What is its conjugate acid?

7.

What is the

p

K

a

of a compound that at

pH

=

7.2

has a 10 times greater concentration in its basic form than

in its acidic form?

8.

a.

What products are formed from the following reaction?

+

3

4

CH OH + NH

b.

Does the reaction favor reactants or products?

9.

A compound has a

K

a

=

6.3

*

10

-

9

.

What is its approximate

p

K

a

(that is, between what two integers)?