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Spectroscopy Problems

25

Copyright © 2017 Pearson Education, Inc.

45.

Identify the alcohol that gives the following

1

H NMR

spectrum.

5

4

3

2

1

0

4

1

3

6

46.

Identify the compound with molecular formula

C

6

H

12

O

2

that gives the following

1

H NMR

data. The number

of hydrogens responsible for each signal is given in parentheses.

1.1 ppm (6H) doublet

2.2 ppm (2H) quartet

1.7 ppm (3H) triplet

5 ppm (1H) septet

47.

Identify the compound with molecular formula

C

9

H

10

O

that gives the following

1

H NMR

data. The number

of hydrogens responsible for each signal is given in parentheses.

1.4 ppm (2H) multiplet

3.8 ppm (2H) triplet

2.5 ppm (2H) triplet

6.9–7.8 ppm (4H) multiplet

48.

Identify the compound with molecular formula

C

11

H

22

O

that gives the following

1

H NMR

data.

1.1 ppm (18H) singlet

2.2 ppm (4H) singlet

49.

Identify the compound with molecular formula

C

4

H

8

O

that gives the following

1

H NMR

data.

1.6 ppm (4H) multiplet

3.8 ppm (4H) triplet

50.

Identify the compound with molecular formula

C

15

H

14

O

3

that gives the following

1

H NMR

data.

3.8 ppm (6H) singlet

7.7 ppm (4H) doublet

7.3 ppm (4H) doublet